Marvin 10081216532D 36 38 0 0 0 0 999 V2000 12.3832 -14.1731 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 11.9767 -14.8866 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 12.7979 -14.8820 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 11.6656 -16.8323 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 11.2549 -16.1188 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 10.8438 -16.8297 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.8370 -14.8700 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 4.8370 -15.6956 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 5.5501 -16.1021 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.2631 -15.6956 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 6.2631 -14.8700 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 5.5501 -14.4510 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.1245 -14.4573 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.1263 -16.1073 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 3.4101 -15.6977 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.6952 -16.1094 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.4089 -14.8721 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.9792 -15.6997 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9780 -14.8742 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 1.2618 -14.4604 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.6928 -14.4583 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 2.6916 -13.6327 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.4065 -13.2210 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.9756 -13.2231 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.9780 -16.1073 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.9798 -14.4573 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.6942 -14.8742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.4109 -14.4614 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.1252 -14.8784 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.4133 -13.6359 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.8419 -14.4656 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.5520 -14.8826 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 10.5450 -15.7089 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 11.9743 -15.7165 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 11.2639 -14.4687 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 9.8313 -16.1157 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 3 2 1 0 0 0 0 18 19 1 0 0 0 0 7 12 1 0 0 0 0 19 20 1 6 0 0 0 8 9 1 0 0 0 0 19 21 1 0 0 0 0 9 10 1 0 0 0 0 21 22 1 0 0 0 0 10 11 1 0 0 0 0 22 23 2 0 0 0 0 11 12 1 0 0 0 0 22 24 1 0 0 0 0 7 8 1 0 0 0 0 10 25 1 1 0 0 0 7 13 1 1 0 0 0 11 26 1 1 0 0 0 5 4 1 1 0 0 0 26 27 1 0 0 0 0 8 14 1 1 0 0 0 27 28 2 0 0 0 0 6 5 1 0 0 0 0 28 29 1 0 0 0 0 14 15 1 0 0 0 0 28 30 1 0 0 0 0 4 6 1 0 0 0 0 29 31 2 0 0 0 0 15 16 1 0 0 0 0 32 31 1 1 0 0 0 32 33 1 0 0 0 0 15 17 2 0 0 0 0 2 1 1 1 0 0 0 32 35 1 0 0 0 0 33 5 1 0 0 0 0 5 34 1 0 0 0 0 34 2 1 0 0 0 0 2 35 1 0 0 0 0 16 18 2 0 0 0 0 33 36 1 6 0 0 0 M END > CHEBI:65915 > FR901464 > A spiro-epoxide with potent anticancer activity that lowers the mRNA levels of oncogenes and tumour supressor genes. It is isolated from Pseudomonas sp. no.2663. > 3 > (2S,3Z)-5-{[(2R,3R,5S,6S)-6-{(2E,4E)-5-[(3R,4R,5R,7S)-4,7-dihydroxy-7-methyl-1,6-dioxaspiro[2.5]oct-5-yl]-3-methylpenta-2,4-dien-1-yl}-2,5-dimethyltetrahydro-2H-pyran-3-yl]amino}-5-oxopent-3-en-2-yl acetate > C27H41NO8 > 507.61630 > 507.28322 > 0 > C[C@H]1C[C@@H](NC(=O)\C=C/[C@H](C)OC(C)=O)[C@@H](C)O[C@H]1C\C=C(C)\C=C\[C@H]1O[C@](C)(O)C[C@@]2(CO2)[C@@H]1O > InChI=1S/C27H41NO8/c1-16(8-11-23-25(31)27(15-33-27)14-26(6,32)36-23)7-10-22-17(2)13-21(19(4)35-22)28-24(30)12-9-18(3)34-20(5)29/h7-9,11-12,17-19,21-23,25,31-32H,10,13-15H2,1-6H3,(H,28,30)/b11-8+,12-9-,16-7+/t17-,18-,19+,21+,22-,23+,25+,26-,27+/m0/s1 > PJKVJJDQXZARCA-QHYZBLTGSA-N > 146478-72-0 > 8176008 > 146478-72-0 > 17279752; 21226105; 9031664 $$$$