Marvin 09061311152D 37 42 0 0 0 0 999 V2000 3.2847 -16.4463 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8595 -17.2756 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 2.5680 -16.0379 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.3688 -17.0464 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 1.8595 -16.4504 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5763 -17.6839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.0015 -16.0338 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.1436 -17.4464 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 7.5604 -16.3088 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 7.5729 -17.2631 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 6.3643 -17.6839 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 6.7727 -16.9797 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 3.2889 -17.2714 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 7.1561 -16.6839 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 9.0022 -17.2631 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.9062 -17.8256 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.7099 -16.4463 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 8.2896 -16.0254 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.1646 -16.4796 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.0064 -16.4379 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.6602 -16.3046 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5680 -15.2002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.8644 -16.0296 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.4267 -16.0296 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.9973 -15.2002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1553 -16.0463 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 2.5763 -18.4965 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 3.2805 -14.7877 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.2896 -15.1961 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 5.4267 -15.2002 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 6.1476 -16.4421 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.3603 -18.2424 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.7057 -14.7794 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 7.5604 -15.5253 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.9767 -16.7630 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.1561 -15.8587 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.2874 -17.6756 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 2 6 1 0 0 0 0 3 1 1 0 0 0 0 4 10 1 0 0 0 0 5 3 1 0 0 0 0 6 13 1 0 0 0 0 7 1 2 0 0 0 0 8 11 1 6 0 0 0 9 23 1 0 0 0 0 10 9 1 0 0 0 0 11 12 1 0 0 0 0 12 10 1 0 0 0 0 13 1 1 0 0 0 0 14 21 1 0 0 0 0 15 4 1 0 0 0 0 16 4 1 0 0 0 0 17 7 1 0 0 0 0 18 9 1 0 0 0 0 4 19 1 1 0 0 0 20 18 1 0 0 0 0 21 12 1 0 0 0 0 22 3 2 0 0 0 0 23 31 1 0 0 0 0 24 17 1 0 0 0 0 25 7 1 0 0 0 0 26 5 2 0 0 0 0 27 6 2 0 0 0 0 28 22 1 0 0 0 0 29 18 2 0 0 0 0 30 24 2 0 0 0 0 31 24 1 0 0 0 0 8 32 1 0 0 0 0 33 25 1 0 0 0 0 9 34 1 1 0 0 0 12 35 1 6 0 0 0 2 5 1 0 0 0 0 28 25 2 0 0 0 0 15 20 2 0 0 0 0 14 19 1 0 0 0 0 8 16 1 0 0 0 0 8 14 1 0 0 0 0 14 36 1 1 0 0 0 10 37 1 6 0 0 0 M END > CHEBI:68244 > platensimycin B2 > A polycyclic cage that is platensimycin with a 1,3-oxazinane ring fused onto the aromatic ring. It is isolated from Streptomyces platensis. > 3 > 3-[(1S,4aS,6S,7S,9S,9aR)-1,6-dimethyl-2-oxo-1,2,5,6,7,8,9,9a-octahydro-6,9-epoxy-4a,7-methanobenzo[7]annulen-1-yl]-N-(7-hydroxy-2,4-dioxo-3,4-dihydro-2H-1,3-benzoxazin-8-yl)propanamide > C25H26N2O7 > 466.48310 > 466.17400 > 0 > [H][C@]12C[C@]3([H])O[C@@]1(C)C[C@@]1(C2)C=CC(=O)[C@@](C)(CCC(=O)Nc2c(O)ccc4c2oc(=O)[nH]c4=O)[C@]31[H] > InChI=1S/C25H26N2O7/c1-23(16(29)5-8-25-10-12-9-15(20(23)25)34-24(12,2)11-25)7-6-17(30)26-18-14(28)4-3-13-19(18)33-22(32)27-21(13)31/h3-5,8,12,15,20,28H,6-7,9-11H2,1-2H3,(H,26,30)(H,27,31,32)/t12-,15+,20+,23-,24+,25+/m1/s1 > QPYJCWMWYJIYBV-YURBTCIXSA-N > 19317593 > 21214253 $$$$