CDK 1030232201 32 37 0 0 0 0 0 0 0 0999 V2000 0.7144 0.0000 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.0000 -0.4125 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7144 0.0000 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.0000 -1.2375 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4290 -0.4125 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.7144 -1.6500 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7144 -1.6500 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4290 -1.2375 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.1434 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4290 -1.2375 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7144 -2.4750 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7144 -2.4750 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0000 -2.8875 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4290 -2.8875 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0000 -3.7125 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.4290 -3.7125 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -0.7144 -4.1250 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.3816 -3.1625 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.1434 -4.1250 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -0.7144 -4.9500 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0000 -4.5375 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.1101 -3.5742 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.1226 -4.9602 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.7803 -5.4107 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7123 -3.5965 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4290 -5.3625 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7553 -3.0791 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.0467 -4.4197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6319 -4.9156 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5200 -5.7102 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.9211 -4.4000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5840 -5.2453 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 2 0 0 0 0 2 3 1 0 0 0 0 2 4 1 0 0 0 0 5 3 1 0 0 0 0 4 6 2 0 0 0 0 4 7 1 0 0 0 0 5 8 1 0 0 0 0 5 9 1 1 0 0 0 6 10 1 0 0 0 0 6 11 1 0 0 0 0 7 12 2 0 0 0 0 11 13 2 0 0 0 0 12 14 1 0 0 0 0 13 15 1 0 0 0 0 16 14 1 0 0 0 0 17 15 1 0 0 0 0 16 18 1 6 0 0 0 19 16 1 0 0 0 0 17 20 1 0 0 0 0 17 21 1 1 0 0 0 22 18 1 0 0 0 0 23 19 1 0 0 0 0 19 24 1 0 0 0 0 19 25 1 1 0 0 0 20 26 1 0 0 0 0 22 27 1 1 0 0 0 22 28 1 0 0 0 0 22 29 1 0 0 0 0 23 30 1 0 0 0 0 28 31 1 0 0 0 0 28 32 1 0 0 0 0 7 8 1 0 0 0 0 12 13 1 0 0 0 0 16 17 1 0 0 0 0 23 26 1 0 0 0 0 23 28 1 6 0 0 0 24 29 1 0 0 0 0 M END > CHEBI:216925 > Talaromyolide K > 2 > (1S,6R,14R,17R,19S,22S)-10,17,19-trihydroxy-6,14,18,18,22-pentamethyl-7,13,23-trioxahexacyclo[17.3.1.01,14.03,12.04,9.017,22]tricosa-3(12),4(9),10-trien-8-one > C25H32O7 > 444.524 > 444.21480 > 0 > O=C1O[C@@H](CC=2C1=C(O)C=C3O[C@@]4(CC[C@]5([C@]6([C@]4(CC23)O[C@](O)(C5(C)C)CC6)C)O)C)C > InChI=1S/C25H32O7/c1-13-10-14-15-12-24-21(4)6-9-25(29,32-24)20(2,3)23(21,28)8-7-22(24,5)31-17(15)11-16(26)18(14)19(27)30-13/h11,13,26,28-29H,6-10,12H2,1-5H3/t13-,21+,22-,23+,24+,25+/m1/s1 > WTANWVPLPGUUBQ-ZHWGPSQHSA-N $$$$