Mrv0541 10141311522D 40 43 0 0 0 0 999 V2000 -3.4708 0.1708 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.7542 -0.2458 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -3.7500 -1.1417 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0458 0.9958 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.0875 -0.3833 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.0458 0.1708 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9292 -1.0542 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -0.6208 0.9958 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.4708 0.9958 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.3333 1.4083 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0958 1.4042 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.8083 0.9833 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7542 1.4042 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.3333 -0.2417 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6208 0.1708 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.0958 2.2250 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.2083 -1.4625 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.5250 1.3917 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5000 -1.0458 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7833 -1.4542 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.1667 -1.8542 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.6458 -1.4458 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0708 -1.0375 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.8167 2.6333 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.8042 0.1583 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.1833 1.4083 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.5292 2.2167 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2042 -2.2875 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.1917 0.5833 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3583 -1.0292 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0750 -1.4333 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.2458 2.6250 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.6167 2.6417 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0750 -0.2125 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7875 -1.0167 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3542 -0.2042 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5042 -1.4250 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7833 -0.1917 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.2167 -1.0083 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0458 -0.6542 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 2 1 1 0 0 0 0 3 5 1 0 0 0 0 4 6 1 0 0 0 0 5 1 1 0 0 0 0 6 2 1 0 0 0 0 7 2 1 0 0 0 0 8 15 1 0 0 0 0 9 1 1 0 0 0 0 10 4 1 0 0 0 0 11 8 1 6 0 0 0 12 11 1 0 0 0 0 13 9 1 0 0 0 0 14 6 2 0 0 0 0 15 14 1 0 0 0 0 16 11 1 0 0 0 0 7 17 1 1 0 0 0 18 12 1 0 0 0 0 19 17 1 0 0 0 0 20 19 2 0 0 0 0 21 3 2 0 0 0 0 22 23 2 0 0 0 0 23 20 1 0 0 0 0 24 16 1 0 0 0 0 25 12 2 0 0 0 0 26 9 2 0 0 0 0 27 24 1 0 0 0 0 28 17 2 0 0 0 0 1 29 1 6 0 0 0 30 22 1 0 0 0 0 31 30 1 0 0 0 0 27 32 1 1 0 0 0 16 33 1 1 0 0 0 34 23 1 0 0 0 0 35 31 1 0 0 0 0 36 30 1 0 0 0 0 37 35 1 0 0 0 0 38 35 1 0 0 0 0 39 37 1 0 0 0 0 2 40 1 6 0 0 0 7 3 1 0 0 0 0 13 4 2 0 0 0 0 10 8 2 0 0 0 0 27 18 1 0 0 0 0 M END > CHEBI:68980 > longirostrerone A > An azaphilone that is 9,9a-dihydro-6H-furo[2,3-h]isochromene-6,8(6aH)-dione substituted by a 4-hydroxy-2-methyl-6-oxocyclohexyl group at position 3, a methyl group at position 6a and a 4,6,8-trimethyldeca-2,4-dienoyl group at position 9. Isolated from Chaetomium longirostre, it exhibits cytotoxic and antimalarial activities. > 3 > CHEBI:68771 > 3-(4-hydroxy-6-methyl-2-oxocyclohexyl)-18-(4,6,8-trimethyldeca-2,4-dienoyl)-(7R)-7-methyl-8,18-dihydro-7H-furo[2,3-h]isochromene-6,17-dione > (6aR,9S,9aR)-3-[(1S,2S,4R)-4-hydroxy-2-methyl-6-oxocyclohexyl]-6a-methyl-9-[(2E,4E)-4,6,8-trimethyldeca-2,4-dienoyl]-9,9a-dihydro-6H-furo[2,3-h]isochromene-6,8(6aH)-dione > C32H40O7 > 536.65580 > 536.27740 > 0 > CCC(C)CC(C)\C=C(C)\C=C\C(=O)[C@@H]1[C@@H]2C3=COC(=CC3=CC(=O)[C@]2(C)OC1=O)[C@@H]1[C@@H](C)C[C@@H](O)CC1=O > InChI=1S/C32H40O7/c1-7-17(2)10-19(4)11-18(3)8-9-24(34)29-30-23-16-38-26(28-20(5)12-22(33)15-25(28)35)13-21(23)14-27(36)32(30,6)39-31(29)37/h8-9,11,13-14,16-17,19-20,22,28-30,33H,7,10,12,15H2,1-6H3/b9-8+,18-11+/t17?,19?,20-,22+,28+,29+,30-,32-/m0/s1 > IAPUSMZQQSXGDI-QXHNIIHBSA-N > 22123575 > 22004007 $$$$