InChI=1S/C25H22O9/c1- 31- 20- 7- 13(2- 4- 15(20) 28) 25- 23(11- 26) 33- 21- 6- 12(3- 5- 18(21) 34- 25) 19- 10- 17(30) 24- 16(29) 8- 14(27) 9- 22(24) 32- 19/h2- 9,19,23,25- 29H,10- 11H2,1H3/t19- ,23+,25+/m0/s1 |
CRPGUMMYQABYES-DNVKUUNQSA-N |
[H][C@]1(CC(=O)c2c(O)cc(O)cc2O1)c1ccc2O[C@@]([H])([C@@H](CO)Oc2c1)c1ccc(O)c(OC)c1 |
|
metabolite
Any intermediate or product resulting from metabolism. The term 'metabolite' subsumes the classes commonly known as primary and secondary metabolites.
|
|
hepatoprotective agent
Any compound that is able to prevent damage to the liver.
|
|
View more via ChEBI Ontology
(2S)- 5,7- dihydroxy- 2- [(2R,3R)- 2- (4- hydroxy- 3- methoxyphenyl)- 3- (hydroxymethyl)- 2,3- dihydro- 1,4- benzodioxin- 6- yl]- 2,3- dihydro- 4H- chromen- 4- one
|
4772951
|
Reaxys Registry Number
|
Reaxys
|
70815-32-6
|
CAS Registry Number
|
KEGG COMPOUND
|
Nyiredy S, Samu Z, Szücs Z, Gulácsi K, Kurtán T, Antus S (2008) New insight into the biosynthesis of flavanolignans in the white-flowered variant of Silybum marianum. Journal of chromatographic science 46, 93-96 [PubMed:18366865] [show Abstract] It has been demonstrated that besides the known flavanolignan constituents of the white-flowered variant of Silybum marianum, (-)-silandrin A (3a) and (-)-isosilandrin A (4a); their trans-benzodioxane diastereomers, (-)-silandrin B (3b) and (-)-isosilandrin B (4b), are also produced by the plant. Moreover, the isolation of their cis-benzodioxane diastereomers, (-)-isocisilandrin (5) and cisilandrin (6), confirm that the previously proposed biosynthetic pathway involving a nonselective O-beta coupling is correct. | Szilági I, Tétényi P, Antus S, Seligmann O, Chari VM, Seitz M, Wagner H (1981) [Structure of silandrin and silymonin, two new flavanolignans from a white blooming Silybum marianum variety]. Planta medica 43, 121-127 [PubMed:17402024] [show Abstract] The structures of two flavanolignans, (-) silandrin and (+) silymonin, from a white flowering variety of Silybum marianum, have been elucidated as 3-desoxy-isosilybin and 3-desoxy-silydianin partly by spectroscopic investigations, partly by chemical transformation into other derivatives and their partial synthesis. In addition 5,7-dihydroxy-chromone has been isolated as a new compound. |
|