CHEBI:87749 - prenyl-FMN

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ChEBI Name prenyl-FMN
ChEBI ID CHEBI:87749
Definition A flavin mononucleotide resulting from the formal dehydrogenation of prenyl-FMNH2. It is an essential cofactor for the decarboxylase enzymes UbiD (Fdc1).
Stars This entity has been manually annotated by the ChEBI Team.
Supplier Information No supplier information found for this compound.
Download Molfile XML SDF
Formula C22H29N4O9P
Net Charge 0
Average Mass 524.462
Monoisotopic Mass 524.16722
InChI InChI=1S/C22H29N4O9P/c1-10-7-12-16-15(11(10)2)22(3,4)5-6-25(16)17-19(23-21(31)24-20(17)30)26(12)8-13(27)18(29)14(28)9-35-36(32,33)34/h6-7,13-14,18,27-29H,5,8-9H2,1-4H3,(H3-,23,24,30,31,32,33,34)/t13-,14+,18-/m0/s1
InChIKey KOUJZPGFPGLHCZ-IYOUNJFTSA-N
SMILES C=12N=C(NC(C1[N+]=3C=4C(N2C[C@@H]([C@@H]([C@@H](COP(O)(O)=O)O)O)O)=CC(=C(C4C(C)(CC3)C)C)C)=O)[O-]
Roles Classification
Biological Role(s): cofactor
An organic molecule or ion (usually a metal ion) that is required by an enzyme for its activity. It may be attached either loosely (coenzyme) or tightly (prosthetic group).
(via flavin mononucleotide )
View more via ChEBI Ontology
ChEBI Ontology
Outgoing prenyl-FMN (CHEBI:87749) has functional parent D-ribitol 5-phosphate (CHEBI:16246)
prenyl-FMN (CHEBI:87749) has functional parent FMN (CHEBI:17621)
prenyl-FMN (CHEBI:87749) has role cofactor (CHEBI:23357)
prenyl-FMN (CHEBI:87749) is a flavin mononucleotide (CHEBI:24041)
prenyl-FMN (CHEBI:87749) is a organic heterotetracyclic compound (CHEBI:38163)
prenyl-FMN (CHEBI:87749) is a zwitterion (CHEBI:27369)
prenyl-FMN (CHEBI:87749) is conjugate acid of prenyl-FMN(2−) (CHEBI:87746)
Incoming prenyl-FMN(2−) (CHEBI:87746) is conjugate base of prenyl-FMN (CHEBI:87749)
IUPAC Name
1-deoxy-5-O-phosphono-1-(3,3,4,5-tetramethyl-9-oxido-11-oxo-2,3,10,11-tetrahydro-7H-quinolino[1,8-fg]pteridin-12-ium-7-yl)-D-ribitol
Synonyms Sources
prenylated FMN ChEBI
prFMN ChEBI
Citation
Payne KA, White MD, Fisher K, Khara B, Bailey SS, Parker D, Rattray NJ, Trivedi DK, Goodacre R, Beveridge R, Barran P, Rigby SE, Scrutton NS, Hay S, Leys D (2015)
New cofactor supports α,β-unsaturated acid decarboxylation via 1,3-dipolar cycloaddition.
Nature 522, 497-501 [PubMed:26083754]
[show Abstract]
Last Modified
01 September 2015