CHEBI:62814 - heme d cis-diol(2−)

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ChEBI Name heme d cis-diol(2−)
ChEBI ID CHEBI:62814
ChEBI ASCII Name heme d cis-diol(2-)
Definition A dicarboxylic acid dianion resulting from the removal of a proton from both of the carboxy groups of heme d cis-diol.
Stars This entity has been manually annotated by the ChEBI Team.
Supplier Information No supplier information found for this compound.
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Formula C34H32FeN4O6
Net Charge -2
Average Mass 648.48600
Monoisotopic Mass 648.16822
InChI InChI=1S/C34H36N4O6.Fe/c1-7-20-17(3)23-13-24-19(5)22(9-10-31(39)40)28(37-24)16-30-34(44,12-11-32(41)42)33(6,43)29(38-30)15-27-21(8-2)18(4)25(36-27)14-26(20)35-23;/h7-8,13-16,43-44H,1-2,9-12H2,3-6H3,(H4,35,36,37,38,39,40,41,42);/q;+2/p-4/t33-,34+;/m0./s1
InChIKey GFRHEDKPMCXPFU-XCVPDAMTSA-J
SMILES Cc1c(C=C)c2C=C3[N+]4=C(C=c5c(CCC([O-])=O)c(C)c6=CC7=[N+]8C(=Cc1n2[Fe--]48n56)C(C=C)=C7C)[C@](O)(CCC([O-])=O)[C@@]3(C)O
Roles Classification
Biological Role(s): cofactor
An organic molecule or ion (usually a metal ion) that is required by an enzyme for its activity. It may be attached either loosely (coenzyme) or tightly (prosthetic group).
View more via ChEBI Ontology
ChEBI Ontology
Outgoing heme d cis-diol(2−) (CHEBI:62814) has role cofactor (CHEBI:23357)
heme d cis-diol(2−) (CHEBI:62814) is a dicarboxylic acid dianion (CHEBI:28965)
heme d cis-diol(2−) (CHEBI:62814) is conjugate base of heme d cis-diol (CHEBI:62811)
Incoming heme d cis-diol (CHEBI:62811) is conjugate acid of heme d cis-diol(2−) (CHEBI:62814)
IUPAC Name
{3,3'-[(2RS,3SR)-7,12-diethenyl-2,3-dihydroxy-3,8,13,17-tetramethyl-2,3-dihydroporphyrin-2,18-diyl-κ4N21,N22,N23,N24]dipropanoato(4−)}ferrate(2)
Synonyms Sources
ferroheme d cis-diol(2−) ChEBI
ferroheme d(2−) ChEBI
haem d cis-diol(2−) ChEBI
heme d cis-diol UniProt
heme d(2−) ChEBI
Manual Xref Database
HEME_D MetaCyc
View more database links
Citations
Murshudov GN, Grebenko AI, Barynin V, Dauter Z, Wilson KS, Vainshtein BK, Melik-Adamyan W, Bravo J, Ferrán JM, Ferrer JC, Switala J, Loewen PC, Fita I (1996)
Structure of the heme d of Penicillium vitale and Escherichia coli catalases.
The Journal of biological chemistry 271, 8863-8868 [PubMed:8621527]
[show Abstract]
Bravo J, Verdaguer N, Tormo J, Betzel C, Switala J, Loewen PC, Fita I (1995)
Crystal structure of catalase HPII from Escherichia coli.
Structure (London, England : 1993) 3, 491-502 [PubMed:7663946]
[show Abstract]
Last Modified
26 July 2019