| Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula SO2. It is a colorless gas with a pungent smell that is responsible for the odor of burnt matches. It is released naturally by volcanic activity and is produced as a by-product of copper extraction and the burning of sulfur-bearing fossil fuels.
Sulfur dioxide is somewhat toxic to humans, although only when inhaled in relatively large quantities for a period of several minutes or more. It was known to medieval alchemists as "volatile spirit of sulfur".
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Escherichia coli
(NCBI:txid562)
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PubMed
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Escherichia coli metabolite
Any bacterial metabolite produced during a metabolic reaction in Escherichia coli.
food bleaching agent
A food additive that is used for the purpose of decolourising food.
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refrigerant
A substance used in a thermodynamic heat pump cycle or refrigeration cycle that undergoes a phase change from a gas to a liquid and back. Refrigerants are used in air-conditioning systems and freezers or refrigerators and are assigned a "R" number (by ASHRAE - formerly the American Society of Heating, Refrigerating and Air Conditioning Engineers), which is determined systematically according to their molecular structure.
food bleaching agent
A food additive that is used for the purpose of decolourising food.
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View more via ChEBI Ontology
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dioxidosulfur
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sulfur dioxide
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[SO2]
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IUPAC
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oxosulfane oxide
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PDBeChem
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R-764
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ChEBI
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Schwefel(IV)-oxid
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ChEBI
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Schwefeldioxid
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ChemIDplus
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SO2
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KEGG COMPOUND
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SO2
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IUPAC
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Sulfur dioxide
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KEGG COMPOUND
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SULFUR DIOXIDE
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PDBeChem
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sulfurous anhydride
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NIST Chemistry WebBook
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sulfurous oxide
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NIST Chemistry WebBook
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sulphur dioxide
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NIST Chemistry WebBook
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1443
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Gmelin Registry Number
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Gmelin
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7446-09-5
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CAS Registry Number
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KEGG COMPOUND
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7446-09-5
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CAS Registry Number
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ChemIDplus
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7446-09-5
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CAS Registry Number
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NIST Chemistry WebBook
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Mohammedamin JK, Shekha YA (2024)
Indoor sulfur dioxide prediction through air quality modeling and assessment of sulfur dioxide and nitrogen dioxide levels in industrial and non-industrial areas.
Environmental monitoring and assessment 196, 463 [PubMed:38642156]
[show Abstract]
In this study, the levels of sulfur dioxide (SO2) and nitrogen dioxide (NO2) were measured indoors and outdoors using passive samplers in Tymar village (20 homes), an industrial area, and Haji Wsu (15 homes), a non-industrial region, in the summer and the winter seasons. In comparison to Haji Wsu village, the results showed that Tymar village had higher and more significant mean SO2 and NO2 concentrations indoors and outdoors throughout both the summer and winter seasons. The mean outdoor concentration of SO2 was the highest in summer, while the mean indoor NO2 concentration was the highest in winter in both areas. The ratio of NO2 indoors to outdoors was larger than one throughout the winter at both sites. Additionally, the performance of machine learning (ML) approaches: multiple linear regression (MLR), artificial neural network (ANN), and random forest (RF) were compared in predicting indoor SO2 concentrations in both the industrial and non-industrial areas. Factor analysis (FA) was conducted on different indoor and outdoor meteorological and air quality parameters, and the resulting factors were employed as inputs to train the models. Cross-validation was applied to ensure reliable and robust model evaluation. RF showed the best predictive ability in the prediction of indoor SO2 for the training set (RMSE = 2.108, MAE = 1.780, and R2 = 0.956) and for the unseen test set (RMSE = 4.469, MAE = 3.728, and R2 = 0.779) values compared to other studied models. As a result, it was observed that the RF model could successfully approach the nonlinear relationship between indoor SO2 and input parameters and provide valuable insights to reduce exposure to this harmful pollutant. | Meo SA, Salih MA, Al-Hussain F, Alkhalifah JM, Meo AS, Akram A (2024)
Environmental pollutants PM2.5, PM10, carbon monoxide (CO), nitrogen dioxide (NO2), sulfur dioxide (SO2), and ozone (O3) impair human cognitive functions.
European review for medical and pharmacological sciences 28, 789-796 [PubMed:38305621]
[show Abstract]
ObjectiveEnvironmental pollution is an emerging global public health problem across the world and causes serious threats to ecosystems, human health, and the planet. This study is designed to explore the impact of environmental pollution particulate matter PM2.5, PM10, carbon monoxide (CO), nitrogen dioxide (NO2), sulfur dioxide (SO2), and ozone (O3) on cognitive functions in students from schools located in or away from air-polluted areas.Subjects and methodsIn this study, two schools were selected: one was located near a traffic-polluted area (school #1), and the second was in an area away from the traffic-polluted area (school #2). In this study, a total of 300 students were recruited: 150 (75 male and 75 female) students from school #1 located in a traffic-polluted area, and 150 students (75 male and 75 female) from school #2 located away from a traffic polluted area. The overall average age of students was 13.53±1.20 years. The students were selected based on age, gender, health status, height, weight, BMI, ethnicity, and homogenous socio-economic and educational status. The pollutants PM2.5, PM10, CO, NO2, O3, and SO2 were recorded in the surrounding environment. The overall mean concentration of environmental pollutants in school #1 was 35.00±0.65 and in school #2 was 29.95±0.32. The levels of airborne particles were measured, and the cognitive functions were recorded using the Cambridge Neuropsychological Test Automated Battery (CANTAB). The students performed the cognitive functions tasks, including the attention switching task (AST), choice reaction time (CRT), and motor screening task (MOT).ResultsThe results revealed that the AST-Mean 928.34±182.23 vs. 483.79±146.73 (p=0.001), AST-mean congruent 889.12±197.12 vs. 473.30±120.11 (p=0.001), AST-mean in-congruent 988.98±201.27 vs. 483.87±144.57 (p=0.001), CRT-Mean 721.36±251.72 vs. 418.17±89.71 (p=0.001), and MOT-Mean 995.07±394.37 vs. 526.03±57.83 (p=0.001) were significantly delayed among the students who studied in school located in the traffic polluted area compared to students who studied in school which was located away from the traffic-polluted area.ConclusionsEnvironmental pollution was significantly higher in motor vehicle-congested areas. Cognitive functions were impaired among the students who were studying in a school located in a polluted area. The results further revealed that the students studying in schools located in environmentally polluted areas have attention, thinking, and decision-making abilities related to cognitive function impairment. | Powell D, Feinstein AD, Lee EKH, Zhang M, Tsai SM, Taylor J, Kirk J, Bell T, Barstow JK, Gao P, Bean JL, Blecic J, Chubb KL, Crossfield IJM, Jordan S, Kitzmann D, Moran SE, Morello G, Moses JI, Welbanks L, Yang J, Zhang X, Ahrer EM, Bello-Arufe A, Brande J, Casewell SL, Crouzet N, Cubillos PE, Demory BO, Dyrek A, Flagg L, Hu R, Inglis J, Jones KD, Kreidberg L, López-Morales M, Lagage PO, Meier Valdés EA, Miguel Y, Parmentier V, Piette AAA, Rackham BV, Radica M, Redfield S, Stevenson KB, Wakeford HR, Aggarwal K, Alam MK, Batalha NM, Batalha NE, Benneke B, Berta-Thompson ZK, Brady RP, Caceres C, Carter AL, Désert JM, Harrington J, Iro N, Line MR, Lothringer JD, MacDonald RJ, Mancini L, Molaverdikhani K, Mukherjee S, Nixon MC, Oza AV, Palle E, Rustamkulov Z, Sing DK, Steinrueck ME, Venot O, Wheatley PJ, Yurchenko SN (2024)
Sulfur dioxide in the mid-infrared transmission spectrum of WASP-39b.
Nature 626, 979-983 [PubMed:38232945]
[show Abstract]
The recent inference of sulfur dioxide (SO2) in the atmosphere of the hot (approximately 1,100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations1-3 suggests that photochemistry is a key process in high-temperature exoplanet atmospheres4. This is because of the low (<1 ppb) abundance of SO2 under thermochemical equilibrium compared with that produced from the photochemistry of H2O and H2S (1-10 ppm)4-9. However, the SO2 inference was made from a single, small molecular feature in the transmission spectrum of WASP-39b at 4.05 μm and, therefore, the detection of other SO2 absorption bands at different wavelengths is needed to better constrain the SO2 abundance. Here we report the detection of SO2 spectral features at 7.7 and 8.5 μm in the 5-12-μm transmission spectrum of WASP-39b measured by the JWST Mid-Infrared Instrument (MIRI) Low Resolution Spectrometer (LRS)10. Our observations suggest an abundance of SO2 of 0.5-25 ppm (1σ range), consistent with previous findings4. As well as SO2, we find broad water-vapour absorption features, as well as an unexplained decrease in the transit depth at wavelengths longer than 10 μm. Fitting the spectrum with a grid of atmospheric forward models, we derive an atmospheric heavy-element content (metallicity) for WASP-39b of approximately 7.1-8.0 times solar and demonstrate that photochemistry shapes the spectra of WASP-39b across a broad wavelength range. | Yu F, Nair AA, Lauper U, Luo G, Herb J, Morse M, Savage B, Zartarian M, Wang M, Lin S (2024)
Mysteriously rapid rise in Legionnaires' disease incidence correlates with declining atmospheric sulfur dioxide.
PNAS nexus 3, pgae085 [PubMed:38476666]
[show Abstract]
Legionnaires' disease (LD) is a severe form of pneumonia (∼10-25% fatality rate) caused by inhalation of aerosols containing Legionella, a pathogenic gram-negative bacteria. These bacteria can grow, spread, and aerosolize through building water systems. A recent dramatic increase in LD incidence has been observed globally, with a 9-fold increase in the United States from 2000 to 2018, and with disproportionately higher burden for socioeconomically vulnerable subgroups. Despite the focus of decades of research since the infamous 1976 outbreak, substantial knowledge gaps remain with regard to source of exposure and the reason(s) for the dramatic increase in LD incidence. Here, we rule out factors indicated in literature to contribute to its long-term increases and identify a hitherto unexplored explanatory factor. We also provide an epidemiological demonstration that the occurrence of LD is linked with exposure to cooling towers (CTs). Our results suggest that declining sulfur dioxide air pollution, which has many well-established health benefits, results in reduced acidity of aerosols emitted from CTs, which may prolong the survival duration of Legionella in contaminated CT droplets and contribute to the increase in LD incidence. Mechanistically associating decreasing aerosol acidity with this respiratory disease has implications for better understanding its transmission, predicting future risks, and informed design of preventive and interventional strategies that consider the complex impacts of continued sulfur dioxide changes. | Wu Y, Sun J, Li Z, Zhang Z, Luo Z, Chang Y, Wu G, Zhang W, Yu S, Yuan K, Yang X (2024)
Photodissociation dynamics of SO2 via the G̃1B1 state: The O(1D2) and O(1S0) product channels.
The Journal of chemical physics 160, 164311 [PubMed:38661196]
[show Abstract]
Produced by both nature and human activities, sulfur dioxide (SO2) is an important species in the earth's atmosphere. SO2 has also been found in the atmospheres of other planets and satellites in the solar system. The photoabsorption cross sections and photodissociation of SO2 have been studied for several decades. In this paper, we reported the experimental results for photodissociation dynamics of SO2 via the G̃1B1 state. By analyzing the images from the time-sliced velocity map ion imaging method, the vibrational state population distributions and anisotropy parameters were obtained for the O(1D2) + SO(X3Σ-, a1Δ, b1Σ+) and O(1S0) + SO(X3Σ-) channels, and the branching ratios for the channels O(1D2) + SO(X3Σ-), O(1D2) + SO(a1Δ), and O(1D2) + SO(b1Σ+) were determined to be ∼0.3, ∼0.6, and ∼0.1, respectively. The SO products were dominant in electronically and rovibrationally excited states, which may have yet unrecognized roles in the upper planetary atmosphere. | Yang Q, Yang T, Liu X, Liu S, Liu W, Nie L, Chu C, Yang J (2024)
Effects of gas signaling molecule SO2 in cardiac functions of hyperthyroid rats.
The Korean journal of physiology & pharmacology : official journal of the Korean Physiological Society and the Korean Society of Pharmacology 28, 129-143 [PubMed:38414396]
[show Abstract]
Sulfur dioxide (SO2), a novel endogenous gas signaling molecule, is involved in the regulation of cardiac function. Exerting a key role in progression of hyperthyroidism-induced cardiomyopathy (HTC), myocardial fibrosis is mainly caused by myocardial apoptosis, leading to poor treatment outcomes and prognoses. This study aimed to investigate the effect of SO2 on the hyperthyroidism-induced myocardial fibrosis and the underlying regulatory mechanisms. Elisa, Masson staining, Western-Blot, transmission electron microscope, and immunofluorescence were employed to evaluate the myocardial interstitial collagen deposition, endoplasmic reticulum stress (ERS), apoptosis, changes in endogenous SO2, and Hippo pathways from in vitro and in vivo experiments. The study results indicated that the hyperthyroidism-induced myocardial fibrosis was accompanied by decreased cardiac function, and down-regulated ERS, apoptosis, and endogenous SO2-producing enzyme aspartate aminotransferase (AAT)1/2 in cardiac myocytes. In contrast, exogenous SO2 donors improved cardiac function, reduced myocardial interstitial collagen deposition, up-regulated AAT1/2, antagonized ERS and apoptosis, and inhibited excessive activation of Hippo pathway in hyperthyroid rats. In conclusion, the results herein suggested that SO2 inhibited the overactivation of the Hippo pathway, antagonized ERS and apoptosis, and alleviated myocardial fibrosis in hyperthyroid rats. Therefore, this study was expected to identify intervention targets and new strategies for prevention and treatment of HTC. | Turner MD, Sapp J (2023)
Fire and Brimstone: SO2 as a Chemical Weapon in History.
Military medicine 188, 286-288 [PubMed:37192218]
[show Abstract]
Sulfur dioxide (SO2), a chemical produced from the burning of sulfur-containing materials, has a long history in chemical warfare. While it was largely used during ancient sieges, there were numerous proposals to weaponize it for the open battlefield in the early modern age. | Livas CG, Raptis D, Tylianakis E, Froudakis GE (2023)
Multiscale Theoretical Study of Sulfur Dioxide (SO2) Adsorption in Metal-Organic Frameworks.
Molecules (Basel, Switzerland) 28, 3122 [PubMed:37049885]
[show Abstract]
In the present work, we used DFT in order to study the interaction of SO2 with 41 strategically functionalized benzenes that can be incorporated in MOF linkers. The interaction energy of phenyl phosphonic acid (-PO3H2) with SO2 was determined to be the strongest (-10.1 kcal/mol), which is about 2.5 times greater than the binding energy with unfunctionalized benzene (-4.1 kcal/mol). To better understand the nature of SO2 interactions with functionalized benzenes, electron redistribution density maps of the relevant complexes with SO2 were created. In addition, three of the top performing functional groups were selected (-PO3H2, -CNH2NOH, -OSO3H) to modify the IRMOF-8 organic linker and calculate its SO2 adsorption capacity with Grand Canonical Monte Carlo (GCMC) simulations. Our results showed a great increase in the absolute volumetric uptake at low pressures, indicating that the suggested functionalization technique can be used to enhance the SO2 uptake capability not only in MOFs but in a variety of porous materials. | Onetto CA, Kutyna DR, Kolouchova R, McCarthy J, Borneman AR, Schmidt SA (2023)
SO2 and copper tolerance exhibit an evolutionary trade-off in Saccharomyces cerevisiae.
PLoS genetics 19, e1010692 [PubMed:36976798]
[show Abstract]
Copper tolerance and SO2 tolerance are two well-studied phenotypic traits of Saccharomyces cerevisiae. The genetic bases of these traits are the allelic expansion at the CUP1 locus and reciprocal translocation at the SSU1 locus, respectively. Previous work identified a negative association between SO2 and copper tolerance in S. cerevisiae wine yeasts. Here we probe the relationship between SO2 and copper tolerance and show that an increase in CUP1 copy number does not always impart copper tolerance in S. cerevisiae wine yeast. Bulk-segregant QTL analysis was used to identify variance at SSU1 as a causative factor in copper sensitivity, which was verified by reciprocal hemizygosity analysis in a strain carrying 20 copies of CUP1. Transcriptional and proteomic analysis demonstrated that SSU1 over-expression did not suppress CUP1 transcription or constrain protein production and provided evidence that SSU1 over-expression induced sulfur limitation during exposure to copper. Finally, an SSU1 over-expressing strain exhibited increased sensitivity to moderately elevated copper concentrations in sulfur-limited medium, demonstrating that SSU1 over-expression burdens the sulfate assimilation pathway. Over-expression of MET 3/14/16, genes upstream of H2S production in the sulfate assimilation pathway increased the production of SO2 and H2S but did not improve copper sensitivity in an SSU1 over-expressing background. We conclude that copper and SO2 tolerance are conditional traits in S. cerevisiae and provide evidence of the metabolic basis for their mutual exclusivity. These findings suggest an evolutionary driver for the extreme amplification of CUP1 observed in some yeasts. | Martins JBL, Cabral BJC (2023)
Electron binding energies of SO2 at the surface of a water cluster.
The Journal of chemical physics 159, 234301 [PubMed:38099545]
[show Abstract]
The electronic properties of SO2 at the surface of a water cluster were investigated by employing a combination of Born-Oppenheimer molecular dynamics and electron propagator theory (EPT). In our work, we utilized a revised version of the Perdew-Burke-Ernzerhof (PBE) exchange-correlation functional, which incorporates empirical corrections for dispersion interactions in line with a recent study of the air-water interface conducted by Ohto et al. [J. Phys. Chem. Lett. 10(17), 4914-4919 (2019)]. Polarization effects induce a significant broadening of the electron binding energy distribution, as predicted by EPT. This broadening can result in a substantial increase in electron affinity, impacting the chemical reactivity of SO2 at the air-water interface, a topic of significant and recent research interest. We discuss the relationship between electron binding energies (EBEs) and the specific connections of SO2 to water. The results indicate that configurations involving an OS⋯H bond tend to yield higher electron affinities compared to complex formation through S⋯OW bonds. Surprisingly, SO2 molecules not bound to water molecules according to a specific criterion may also exhibit higher electron affinities. This feature can be explained by the role played by the polarization field from water molecules. Our best estimate for the HOMO-LUMO (H-L) gap of SO2 at the surface of a water cluster is 11.6 eV. Very similar H-L gaps are predicted for isolated and micro-solvated SO2. Fukui functions for the gas phase, and the micro-solvated SO2-H2O complex supports the view that the LUMO is predominantly localized on the SO2 moiety. | Luo Z, Zhang Z, Yang S, Zhao Y, Li Z, He Z, Chang Y, Che L, Yuan K, Yang X (2023)
Photodissociation dynamics of SO2 between 193 and 201 nm.
The Journal of chemical physics 159, 024307 [PubMed:37439466]
[show Abstract]
The nonadiabatic interactions between the C̃ state and neighboring electronic states of SO2 have attracted much attention; however, the predissociation mechanisms are not yet completely understood. In this work, the predissociation dynamics of SO2 via its C̃ state have been investigated at λ = 193-201 nm by using the time-sliced velocity map ion imaging technique. The translational energy distributions and the branching ratios of the O(3PJ=2,1,0) spin-orbit products at six photolysis wavelengths have been acquired. The SO(3Σ-) product population gradually decreases in v = 0 and increases in v = 2 as the photolysis wavelength decreases. The branching ratios of O(3P J=2,1,0) products are almost similar at most wavelengths, except at 194.8 nm. Our data suggest that the predissociation between 193 and 201 nm is via an avoided crossing between the C̃ state and the repulsive triplet 23A' state. The state-to-state dynamical pictures shown in this work provide a rigorous test of the potential energy surfaces (PESs) of the SO2 and the nonadiabatic couplings between these PESs. | Liu X, Yang D, Meng Z (2008)
[The effects of SO2 on electric activity learning and memory of rat hippocampal neurons].
Wei sheng yan jiu = Journal of hygiene research 37, 660-663 [PubMed:19238997]
[show Abstract]
ObjectiveTo study the toxicological mechanism of SO2 on central neural system by electrophysiological method.MethodsMale SD rats were housed in exposure chambers and treated at the concentration of 28 mg/m3 SO2 for 7 days (6h/d), while control rats were treated with filtered air in the same condition. Using glass micro-electrodes recording in vivo, the frequencies and numbers of spontaneous discharge in hippocampal CAI neurons were measured. Influences of the learning and memory functions were measured by setting up passive avoidance behavior reflex.ResultsSO2 decreased significantly the neurons spontaneous discharge frequency and prolonged the neurons spontaneous period in hippocampal CAl. SO2 significantly decreased the learning and memory function of rats.ConclusionThe results indicated that SO2 could be a neurotoxin. It could inhibit the hippocampal neurons excitability and affect the learning and memory function of rats. |
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