A member of the class of validamycins that is (1R,2S,3S,4S,6R)-4-amino-6-(hydroxymethyl)cyclohexane-1,2,3-triol in which the hydroxy group at position 1 has been converted to its beta-D-glucoside and in which one of the hydrogens attached to the nitrogen is replaced by a (1R,4R,5R,6S)-4,5,6-trihydroxy-3-(hydroxymethyl)cyclohex-2-en-1-yl group. It is the major validamycin produced by Streptomyces hygroscopicus.
class Information
0
C20H35NO13
- BPDB:677
- CAS:37248-47-8
- HMDB:HMDB0036592
- KEGG:C12112
- KNApSAcK:C00018797
- MetaCyc:VALIDAMYCIN-A
- Pesticides:validamycin
- PMID:18943474
- PMID:20952185
- PMID:22036231
- PMID:22481376
- PMID:22521597
- PMID:23295203
- PMID:23340099
- PMID:25060680
- PMID:25102722
- PMID:25236210
- PMID:3269390
- PMID:3570986
- PMID:5549382
- PMID:6548220
- PMID:9242988
- PMID:9813313
- Reaxys:5319831
- Wikipedia:Validamycin
chebi_ontology
InChI=1S/C20H35NO13/c22-3-6-1-8(12(26)15(29)11(6)25)21-9-2-7(4-23)19(17(31)13(9)27)34-20-18(32)16(30)14(28)10(5-24)33-20/h1,7-32H,2-5H2/t7-,8+,9+,10-,11-,12+,13+,14-,15+,16+,17-,18-,19-,20+/m1/s1
JARYYMUOCXVXNK-CSLFJTBJSA-N
497.49080
497.21084
OC[C@H]1C[C@H](N[C@H]2C=C(CO)[C@@H](O)[C@H](O)[C@H]2O)[C@H](O)[C@@H](O)[C@@H]1O[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O
class Relations
- polyol
- secondary amino compound
- validamycins
- antibiotic fungicide
- has rolerosomeEC 2.4.1.231 [alpha,alpha-trehalose phosphorylase (configuration-retaining)] inhibitor
- has rolerosomeEC 2.4.1.64 (alpha,alpha-trehalose phosphorylase) inhibitor
- has rolerosomeEC 3.2.1.28 (alpha,alpha-trehalase) inhibitor
- has rolerosomeantifungal agrochemical
- is conjugate base ofsomevalidamycin A(1+)